ABSTRACT
The seeds from this pear were oven dried
at 100oC-125oC to a moisture content level of 29%. The
seeds were subjected to proximate analysis to determine the percentage of the
moisture, fat, crude fibre, crud content which resulted to the values of 29%,
19.6%, 25.5%, respectively. Then the dried sample was pulverized by using
grinding mill and the oil was extracted by solvent extraction using n-hexane.
The oil extracted were analyzed for the chemical properties i.e. (Acid value,
saponification value, peroxide value, iodine value) etc. the values obtained
are respectively 8.1gm/KOH/gm, 201.96gm/KOH/gm, 2.5gm/KOH/gm 3.96gm/iodine/gm
and Physical properties i.e. ( Ph value, specific gravity) which the values
obtained are 5.58 and 0.90. and the The percentage oil yield content is 29.39%.
This physio-chemical characteristic and fatty acid composition of this oil show
that they have industrial potentials.
This project is on Extraction of oil from a
local seed (groundnut oil) and Characterization was carried out using ten
cups of groundnut seeds that was purchased from a local market in Enugu
metropolis. The oil these seeds were in
Enugu using solvent extraction method.
Two different solvents were used in the extraction namely: Ethane and
order to compare their yield, physical and chemical properties.
The extraction was carried out using
32og of size-reduced groundnut with 100ml of 17-hexane while 1.5litres a 15ooml
of ethanol was used on 480g of size reduced groundnut seeds. Ta the end of the extraction operation, the
amount of oil-extracted using17-hexane was observed to be far greater than the
amount of oil extracted using ethanol.
The chemical and physical properties of
the oil were determined by analysis of the oil.
The physical appearance of 17- hexane extract is light yellow in colour
this; true colour of groundnut oil while that the ethanol extract has a light
bown colour. The colour of ethanol on
pigments in the size-reduced groundnut seed.
From
the result obtained, it was deduced that 17-hexane remains the best
solvent for oil extraction while ethanol is not a good solvent for oil
extraction.
The physical and chemical constants/
properties determined were:
PHYSICAL PROPERTIES:
a)Solidification point.
b)Melting point
c)Specific gravity
d)Moisture content.
CHEMICAL PROPERTIES
a)Acid value
b)Specifications value
c)Peroxide value
d)Iodine value
Form the analysis camied out on the
extracted oil, the results obtained shows that the extracted oil is a pure
groundnut oil because the iodine value which shows the purity of an oil is
close to literature value. The iodine
value of he oil extracted is 79.95 while the literature value (standard value)
rangers from 94-102.
TABLE OF CONTENT
Title page
Approval page
Letter of transmittal
Dedication
Acknowledgement
Abstract
Table of contents
CHAPTER ONE.
1.1
Introduction
1.2
Scope / objectives of the project.
CHAPTER TWO
2.0
Literature Review
2.1
Groundnut Seed
2.2
Adaptation
2.3
Diseases Of Groundnut
2.4
Extraction
2.5
Methods Of Oil Extraction
2.6
Rendering
2.7
Mechanical Expression
2.8
Solvent Extraction
2.9
Groundnut Oil Extraction
2.9.1Factors Affecting Rate Of Leaching
2.9.2Factors Governing Choice Of Solvent
2.9.3Leaching Of Vegetable Seeds
2.9.4Theories Of Solvet Extractions
2.9.5Undissolved Oil Theory
2.9.6Physical Properties Of Vegetable
Oil
2.9.7Characterization Of Oils
2.9.8Saponification Value
2.9.9Iodine Value
CHAPTER THREE
3.0
Experimental Methods
3.1
Preparation Of The Seeds
3.2
Particle Size Reduction
3.3
Extraction And Distillation
3.4
Uses Of Soxlilet Extractor
3.5
Distillation
3.6
Solidification Point
3.7
Melting Point
3.8
Specific Gravity
3.9
Determination Of Moisture Content
3.10 Determination Of Chemical
Properties
3.11 Determination Of Acid Value
3.12 Specification Value
3.13 Peroxide Value
3.14 Iodine Value
CHAPTER FOUR
4.0
Experimental Results
CHAPTER FIVE
5.0
Discussion
CHAPTER SIX
6.1
Conclusion / Recommendation
6.2
References
6.3
Appendices.
CHAPTER ONE
INTRODUCTION
1.1 Background of the Study
In the major world, one major source of
protein and vegetable oil is from oil seeds fruits (Williams M. A. 1996). Oil
constitutes a well-defined class of naturally occurring substance. It is
greasy, being soluble in organic solvents but insoluble in polar solvents such
as water. Oil is a liquid at room temperature. Commercially, oil as well as
fats is sourced from certain plant groups mostly seeds and nuts and some parts
of animal within which they occur in relatively large quantity in an easily
available form (McGraw-Hill, 1997).
The existence of oil in certain plants has
been known for century of years (Ogbu 2005.Oil can be grouped into edible and
non-edible oil depending on the amount of unsaponified matters and impurities
contained therein. Edible oil extracted from African pear, bread fruits, cashew
nut, peanut etc. are examples of vegetable oil which are naturally occurring
esters of higher fatty acids and glycerol, and are predominantly triglycerides with
traces of mono and diglycerides, sterples, anti-oxidants, vitamins, saturated
and unsaturated free fatty acids and other minor constituents. They are widely
distributed in nature and were first consumed as food. Later, oils were
discovered to be used as renewable raw materials for variety of non-food
production. For instance; soaps, creams, disinfectants, paints, enamels, inks
etc.
Oil can be extracted from various seeds;
however, this work focuses on one particular seeds, (African pear seeds).
Extraction can be defined as a separation process consisting in the separation
of a substance from a matrix; The first step in obtaining oil from the seed is
to remove the seed-coat and husk in a process referred to as dehulling. i
separating the chaff and dried by placing the seeds under the sun or by heating
carefully on the fire for a short while. In the case of using crude means to
extract the oil, drying can be followed by warming which ensures more oil
yield. Once this is done, the next step is to begin the crucial extraction
process.
These edible oils are consumed in
various ways; the liquid form are used for cooking in warmer climate, in the
western world, they are eaten in spreadable form,
Dacryodes edulis is cultivated in large
quantity in South- Eastern Nigeria and other African countries like Cameroon,
Sierra Leone, Uganda, Malaysia, Liberia, and Zaire. There are two varieties of
Dacryodes edulis in Nigeria- D.e.var. edulis and D.e.var. parvicarpa (Isaac and
Ekpa, 2009). The fruits and seeds of this plant have been found to contain
reasonable amounts of oil (Ikhuoria and Maliki, 2007; Arisa and Lazarus, 2008).
African pear oil contains the following acids: palmitic acid (9.06%), stearic
acid (15.46%), oleic acid (26.63%) and linoleic acid (30.85%) (Ikhuoria and
Maliki, 2007) Umoti and Okyi (1987) gave the fatty acid composition and the
range of fatty acids in African pear oil as follows: palmitic acid 47.89% (35 –
65%), oleic acid 31.25% (16 – 35%) and linoleic acid 17.5% (14 – 27%). The
physicochemical properties of African pear oil determined by Ikhuoria and
Maliki (2007) are average melting point (80 0C), refractive index (1.456),
viscosity (0.33 poise), free fatty acid (1.100%), saponification value (143.760
mgKOH/g), iodine value (44.079 gI2/100g), acid value (15.280 mgKOH/g), ester
value (128.480) and unsaponifiable matter (53.920%). On the other hand, Umoti
and Okyi (1987) determined saponification value, iodine value and specific
gravity of APO as 201.4 mgKOH/g, 59.6 gI2/100g and 0.9 respectively. Adequate
development of this oil could contribute to the nation’s demand for vegetable
oils for surface coatings and other industrial applications.
Oils are extracted in two primary ways,
by mechanical pressing, or heating and with petroleum solvents. Before the
1940’s, mechanical pressing was the primary method used. Mechanical extraction,
however, had its limits in terms of oil recovery. Because pressing generates
heat and high temperatures which damage both the oil and meal, an oil content
of the press cake below 5-6% was difficult to achieve. Solvent extraction was
developed because it allows a more complete extraction at lower temperatures.
It begins to be economically attractive where large quantities of seed can be
processed (at least 200 tons per day for continuous-feed processes); where
storage, transportation, power, water, and solvent supply are adequate; and
where occupational safety and training standards can be enforced. This work
focuses on the extraction of oil from two local seeds using n-hexane in a
soxhlet apparatus, determine the physicochemical properties of the oils based
on oil content, pour point, specific gravity, viscosity, refractive index,
iodine value, acid value and peroxide value. This study was designed to
establish the suitability of the oils for domestic and industrial uses.
1.2 Aim of the Study
The
aim of this research is to extract and analyse oil from Dacryode edulis seeds
(African pear seeds)
Research
Objectives
Ø To
determine the percentage, yield of oil from the seed
Ø To
determine the physiochemical properties of the oil extracted;
Ø To
analyze and know the usefulness of the oil extracted.
1.3 Statement of the Problems
In Nigeria, it has been estimated
product to consumption
margin is increasing by thousand tons naturally because of
population growth and raise in the use of edible seed oil like coconut etc. For
several purposes such as soap making, cosmetics, and other industrial purposes.
This situation in particular calls for serious consideration for effective
future planning of reducing utilization of edible seed and maximize non edible
oil seed production in the country.
Also most edible seeds like pears have
been proven to contain reasonable amount of oil which can be applied in so many
ways but in Nigeria we love to use oil from coconut. Ways will be discussed in
how to extract reasonable amount of oil from African pear seeds
1.4 Justification of the Study
The use of edible seed for extraction of
oil has been of great concern recently; this is because of the discoveries base
on the fact that, they are very important to both human and industrial application.
These can cause serious problems if those seeds used are scarce.
Therefore, this research work focus on
the use of non-edible seed (African pear) seeds for extraction of oil.
1.5 Scope of the Study
The purpose of this project work was to
explore the extraction of oil from Dacryode edulis seeds. The study aimed at
extracting oil from African pear via (n-hexane) extraction and analyzing of
oil. The study also aims at determining the physicochemical properties of oil
while observing the kinetic degradation of the oil with a view to determine its
oxidative stability.
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