PHYTOCHEMICAL SCREENING AND ANTIBACTERIAL ACTIVITIES OF THE ETHANOLIC AND AQEUOUS LEAF EXTRACTS OF ALCHORNEA CORDIFOLIA (EUPHORBIACEAE) AND SIDA ACUTA (MALVACEAE) AGAINST SOME BACTERIAL ISOLATES FROM MEAT

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ABSTRACT

 

The ethanolic and aqueous extracts of Alchornea cordifolia and Sida acuta were screened for antibacterial activities against some bacterial isolates from meat. Five (5) genera of bacteria were isolated and used for this work and they included; Staphylococcus aureus, Pseudomonas aeruginosa, Escherichia coli, Salmonella spp and Shigella spp. A weight of 50g of the plants leaves powder was soaked in the solvents for 48-72 hours. The aqueous extract of A. cordifolia gave the highest yield of 10.5g (21%) while the aqueous extract of S. acuta gave the least yield of 7.0g (14%).  The cold maceration extraction method was used for the extraction of the active components in the plant leaves used. For the antibacterial activities, the disc diffusion method was employed while the macro broth dilution method was used to determine the minimum inhibitory concentrations and minimum bactericidal concentrations. The ethanol and aqueous extracts of the two plants showed broad spectrum of activities. The aqueous extract of Alchornea cordifolia had larger zones of inhibition ranging from 3.0 mm – 17 mm and lower M.I.C and M.B.C values that ranged from 3.125 mg/ml - 6.25 mg/ml, while the ethanolic extract had zones of inhibition that ranged from 4.0 mm- 15 mm and M.I.C and M.B.C values that ranged from 6.25 mg/ml- 12.5mg/ml. This result was in contrast to Sida acuta which had higher zones of inhibition that ranged from 5 mm – 18 mm and lower M.I.C and M.B.C values that ranged from 1.563 mg/ml - 3.125 mg/ml in the ethanolic extract. The aqueous extract of S. acuta had lower zones of inhibition that ranged from 5 mm – 15 mm and M.I.C and M.B.C values that ranged from 6.25 m-g/ml – 12.5 mg/ml. The biochemical determinations of the plants revealed the presence of Tannin, Saponin, Terpernoids, Steroids, Alkaloids, Flavonoids, Phenol, and Hydrogen Cyanides in the plants at varying quantities. Steroids were absent in Sida acuta. The results of this this study revealed that the extracts of the leaves of the plants had antibacterial activities against the test organisms hence justifying their forkloric use in the treatment of food borne diseases caused by bacteria.

                                               

 


 

 

                                                     TABLE OF CONTENTS

Title page                                                                                                                                i

Certification page                                                                                                                   ii

Dedication                                                                                                                              iii

Acknowledgements                                                                                                                iv

Abstract                                                                                                                                  v

Table of Contents                                                                                                                   vi

 

CHAPTER ONE                  

1.0           Introduction                                                                                                                1

1.1           Aim and Objectives                                                                                                    3

 

CHAPTER TWO

2.0       Literature Review                                                                                                       4

2.1       Herbal medicine in Nigeria                                                                                        4

2.1.1    Safety and Standardization of Herbal Medicine                                                         5

2.1.2    Status of Herbal Medicine in Nigeria                                                                         6

2.2       Alchornea cordifolia (Euphorbiaceae)                                                                       7

2.2.1    Plant Description                                                                                                        7                                                                                  

2.2.1    Ethno-medicinal Properties of Alchornea cordifolia                                                 8

2.2.2    Phytochemical Constituents of Alchornea cordifolia                                                9

2.3       Sida acuta (Malvaceae)                                                                                              9

 2.3.1   Plant description                                                                                                         10

2.3.2    Traditional uses in folk medicine                                                                               10

2.3.3    Ethano-medicinal properties of Sida acuta                                                                11

2.3.3.1 Antibacterial activities                                                                                               11

2.3.3.2 Antifungal activities                                                                                                   12

2.3.3.3 Antiplasmodial activity                                                                                              12

2.3.3.4 Anti-inflammatory activity                                                                                        13

2.3.3.5 Analgesic activity                                                                                                       13

2.3.3.6 Antiulcer activity                                                                                                        13

2.3.3.7 Hypoglycemic activity                                                                                               13

2.3.3.8 Antipyretic activity                                                                                                     14

2.3.3.8 Hepatoprotective activity                                                                                           14

2.3.3.9 Wound healing activity                                                                                              14

2.3.3.10    Neuropharmacological effects      -                                                                       15

2.3.3.11     Antioxidant activity                                                                                              15

2.3.3.12     Cytotoxicity                                                                                                          15

2.3.3.13     Insecticidal properties                                                                                          16

2.3.3.14     Inhibitory effect on calcium oxalate crystal growth                                             16

2.3.3.15     Cardio-vascular activity                                                                                       16

2.3.3.16 Neutralizing activity against snake venom                                                               17

2.3.3.17 Phytochemical Constituents of sida acuta                                                               17

2.4         Phytochemistry of Medicinal Plants                                                                         17

2.4.1      The Journey of Medicinal Plant Research                                                                19

2.4.2      Biological Activities of Phytochemicals                                                                  20

2.4.3      Classification of Phytochemicals                                                                             20

2.4.4      Phenolics                                                                                                                  21

2.4.5      Phenolic acids                                                                                                           21

2.4.5.1   Activity of Phenolic Acids                                                                                       22

2.4.6.     Flavonoids                                                                                                                23

2.4.6.1   Activity of Flavonoids                                                                                              23

2.4.7.     Tannins                                                                                                                     24

2.4.7.1   Activity of Tannins                                                                                                   25

2.4.8.     Alkaloids                                                                                                                  25

2.4.8.1  Activity of Alkaloids                                                                                                 27

2.4.9.     Terpenoids                                                                                                                27

2.4.9.1   Activity of Terpenes                                                                                                 28

2.4.10    Saponin                                                                                                                     29

2.4.10.1 Activity of Saponins                                                                                                 29

2.5         Mode of Resistance by Some Bacteria Antibiotics                                                  30

2.5.1      Staphylococcus aureus Resistance.                                                                          30

2.5.2      Moraxella catarrhalis Resistance to Beta-lactams.                                                 31

2.5.3      Streptococcus pneumoniae Resistance to Macrolides.                                             32

2.5.4     Pneumococcal Resistance in Tetracyclines and Other Agents                                33

 

CHAPTER THREE

3.0       Materials and Methods                                                                                               34

3.1       Study Area                                                                                                                  34

3.2       Collection, Identification and preparation of plant leaves.                                        34

3.3       Source of Meat                                                                                                           34

3.4       Sterilization of Materials                                                                                            34

3.4       Media Used                                                                                                                34

3.5       Preparation of Media                                                                                                  34

3.6       Isolation of Bacteria                                                                                                   35

3.7       Purification of Isolates and Storage                                                                            35

3.8       Identification and Characterization                                                                            35

3.9       Gram Staining                                                                                                            35

3.10      Biochemical Tests                                                                                                     36

3.10.1   Motility Test                                                                                                              36

3.10.2   Catalase Test                                                                                                              36

3.10.3   Oxidase Test                                                                                                              36

3.10.4   Coagulase Test                                                                                                          26

3.10.5   Citrate Test                                                                                                                37

3.10.6   Indole Test                                                                                                                 37

3.10.7   Urease Test                                                                                                                37

3.10.8   Methyl Red- Voges- Proskauer Test                                                                         38

3.10.9  Triple Sugar Iron Test                                                                                                38

3.11     Ethanol and Aqueous Extraction of Plant Material                                                    38

3.12     Susceptibility Testing                                                                                                             39

3.13     Determination of Minimum Inhibitory Concentration (M.I.C)                                     39

3.14     Determination of Minimum Bactericidal Concentration (M.B.C)                                     40

3.15     Phytochemical Analysis                                                                                             40

3.15.1   Qualitative analysis for the Presence of Phytochemicals in the Plants Studied.            40

3.15.1.1  Test for the Presence of Alkaloids                                                                               40

3.15.1.2  Test for the Presence of Flavonoid                                                                          40

3.15.1.3  Test for the Presence of Phenols.                                                                            41

3.15.1.4  Test for the Presence of Saponin                                                                                        41

3.15.1.5  Test for the Presence of Steroid                                                                                         41

3.15.1.6  Test for the Presence of Tannin.                                                                                         41

3.15.1.7  Test for the Presence of Terpenoids                                                                                     42

3.15.1.8  Test for the Presence of Hydogen Cyanide (HCN)                                                               42

3.15.2    Quantitative determination of the phytochemical constituents of the

           plants studied                                                                                                                         42

3.15.2.1  Alkaloid Determination.                                                                                                     42

3.15.2.2  Flavonoid Determination.                                                                                       43

3.15.2.3  Determination of Phenols.                                                                                       44

3.15.2.4  Determination of Saponins.                                                                                     44

3.15.2.5 Steroid Determination                                                                                              45

3.15.2.6 Tannin Determination                                                                              46

3.15.2.7  Determination of Terpenoids                                                                                  47

3.15.2.8  Determination of Hydrogen Cyanide                                                                      47

3.16    Statistical Analysis                                                                                                      47

 

CHAPTER FOUR

4.0   Results                                                                                                                            48

 

CHAPTER FIVE

5.0   Discussions                                                                                                                                     61

5.1   Conclusion                                                                                                                  65

5.2   Recommendations                                                                                                      65

REFERENCES                                                                                                         66

Appendixs                                                                                                                              83

 

 

  

 

LIST OF TABLES

Table 4.1        Biochemical Test and Morphological Characteristics of Isolates                        50

Table 4.2        Percentage Yield of the Plants                                                                        52

Table 4.3       Antibacterial Activity (Zone of inhibition (mm)) Values of Ethanol

                       Extract of A.cordifolia against Bacteria Isolates from Meat                                     53

Table 4.4        Antimicrobial Activity (Zone of inhibition (mm) Values of

Aqueous Extract of A. cordifolia Against Bacteria Isolates from Meat       54

Table 4.5        Antibacterial Activity (Zone of inhibition (mm) Values of Ethanol

Extract of S. acuta Against Bacteria Isolates from Meat                             55

Table 4.6      Antibacterial Activity (Zone of inhibition (mm) Values of Aqueous

                      Extract of S. acuta Against Bacteria Isolates from Meat.                              56

Table 4.7      Minimum Inhibitory Concentration (MIC) and Minimum

Bactericidal Concentration (MBC) of Ethanol and Aqeuous Leaf

Extracts of Alchornea cordifolia Against Bacterial Isolates from Meat.        57                    

Table 4.8      Minimum Inhibitory Concentration (MIC) and Minimum

Bactericidal Concentration (MBC) of Ethanolic and Aqeuous Leaf Extracts

of Sida acuta on Bacterial Isolates from Meat                                       58

Table 4.9    Qualitative Phytochemical Analysis of Alchornea cordifolia and

                    Sida acuta Leaves                                                                                               59

Table 4.10   Quantitative Pytochemical Analysis of Alchornea cordifolia and

                     Sida acuta Plant Leaves                                                                                    60

 

         

 

 

                                                CHAPTER ONE    

              

1.0                                            INTRODUCTION

The history of the use of herbs in the management of diseases dates back to the time of the early man (Sofowora, 2002; Kafaru, 2004). In herbal medicine, herbs/plants are used in their unaltered form for the treatment of disease. A variety of plants or materials derived from plants have been used for the prevention and treatment of diseases virtually in all cultures (Adedapo et al., 2005). It is also reported that herbs have been used as sources of food and medicinal purposes for centuries and this knowledge has been passed from one generation to another (Adedapo et al., 2005). Medicinal plants also represent a rich source from which antimicrobial agents can be obtained (Kubmarawa et al., 2007). Many pharmaceuticals currently available to physicians have a long history of use as herbal remedies (Elumalai and Eswariah, 2012). Pravin, (2006) reported that about 70% of the human population is dependent (wholly or partially) on plant-based medicines and the World Health Organisation (WHO) estimates that 80% of the population in some Asian and African countries depends on herbal medicine for some aspect of primary health care (WHO, 2008). A majority of Nigerian population still rely on herbal medicine (Eliakim-Ikechukwu and Riman, 2009). Available evidence suggests that some herbal remedies and traditional therapeutic regimes are efficacious and affordable (TMP, 2007).

Antimicrobial drug resistance is a global challenge for the 21st century with the emergence of resistant bacteria strains worldwide (Furin et al., 2011). The increasing prevalence of multi-drug resistant strains of bacteria and the recent appearance of strains with reduced susceptibility to antibiotics raised the specter of untreatable bacterial infections and adds urgency to the search for new infection-fighting strategies (Zy et al., 2005; Rojas et al., 2006).

Medicinal properties of plants are hinged on the presence of bioactive principles such as alkaloids, phenols, tannins, glycosides, saponins, terpeniods, flavonoids, steroids, hydrogen cyanide and essential oils among others. This necessitates the continued screening of medicinal plants, not only to determine the scientific basis for their usage, but also to discover possible new active principles (Karou et al., 2006). The primary benefits of using plant derived medicines are that they are relatively cheaper than synthetic alternatives, offering profound therapeutic benefits and more affordable treatments. Many of the plant materials used in traditional medicine are readily available in rural areas and this has made traditional system of medicine relatively cheaper than modern medicine. Many works have been carried out with the aim of knowing the different antimicrobial and phytochemical constituents of medicinal plants and using them for the treatment of microbial infections as possible alternatives to antibiotics and other chemotherapeutic agents to which many infectious microorganisms have become resistant.

 An example is Hydratics Canadensis, not only does it have antimicrobial activity but also increases blood supply to the spleen releasing mediating compounds (Ijeh et al., 2004). Xytopia aethiopica have an attractive aroma and has been applied in ethno medicine in the treatment of cough, bronchitis, dysentery and female fertilization. Garcina biflavonone have been found to be active against variety or organism like Staphylococcus aureus and Escherichia coli (El-said et al., 2006). It is used in the treatment of liver disorder, bronchitis, as a chewing stick and throat infections (Iwu, 2003). Some extracts of green pepper, garlic and onion have been observed to inhibit the growth of Shigella dysentria, Salmonella typhosa (Lamidi et al., 2005). Ocimum gratissimum is used as vegetable for soup preparations which exhibits hot and spicy taste and are consumed during cold season. It is claimed that spicies and herbs assist in the concentration of the uterus in post-partum women (Murray, 2005). Alchornea cordifolia and Sida acuta are also medicinal herbs in Nigeria used in in treatment of some infectious disease (Lamidi et al., 2005).

The genus Alchornea belongs to the spurge family Euphorbiaceae, which contains about 7500 species in all parts of the world, including trees, shrubs and herbs (Dos et al., 2010). The plant stem extracts have been reported to possess antimicrobial activity and its spectrum of activity has been shown to include the Gram negative bacteria and the Gram positive bacteria (Tona et al., 2000; Banzouzi et al., 2002; Hassan et al., 2006). Its antifungal activity was reported [Kubmarawa et al., 2007].

 However Sida acuta is a marvelous weed that frequently dominates improved pastures, waste and disturbed places such as roadsides (Okwu and Ekeke, 2003). The described pharmacological properties of the plants involve the antiplsamodial, antimicrobial, antioxidant and many other properties. Some studies resulted in the isolation of single compounds while others just demontrated the activity of the crude extracts (Okwu and Ekeke, 2003).

Medicinal plants such as Alchornea cordifolia and Sida acuta have been asserted to provide various culinary and medicinal properties. These medicinal properties exerts bacteriostatic and bacteriocidal effects on some bacteria. These effects have been attributed to the peptides, alkaloids essential oil, flavonoids amongst others which are the major compounds in these plants (Onajobi, 2006).


2.1   AIM AND OBJECTIVES                                   

The aim of this work is to evaluate the antibacterial activity of the ethanol and aqueous extracts of Alchornea cordifolia and Sida acuta leaves against some pathogenic organisms isolated from meat. The objectives are;

1. To characterize and identify pathogenic organisms isolated from meat.

2. To determine the effect of the aqueous and ethanolic extracts of S. acuta and A. cordifolia on some bacteria isolates from meat.

3. To determine the minimum inhibitory concentration and minimum bactericidal concentration of ethanolic and aqueous leaf extracts of Sida acuta and Alchornea cordifolia.

4. To determine the phytochemical composition of Alchornea cordifolia and Sida acuta leaves.   


 

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