EVALUATION OF THE CHEMICAL COMPOSITION, ANTI-OXIDANT AND PHYSICO-CHEMICAL PROPERTIES OF PRODUCTS (JUICE AND JAM) DEVELOPED FROM MALAY ROSE APPLE (SYZYGIUM MALACCENSE)

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ABSTRACT

The potential of some wild growing indigenous fruits such as Malay rose apple (Syzygium malaccense) has remained largely untapped. Most tropical fruits can be processed and preserved in small scale operations using simple techniques. This study was carried out investigate the possibility of producing juice and jam from Malay rose apple and to evaluate the nutritional, anti-oxidant, physico-chemical and organoleptic properties of the product. Malay rose apples were brought from Ndoro market, Abia State. The fruits were purchased from different vendors and pooled to obtain the sample for the study. The juice and jam were prepared using standard methods. The proximate, mineral and vitamin content of the samples were determined using standard AOAC methods. Sensory evaluation of the products was carried out using a 9-point hedionic scale. All tests were carried out in duplicates and means and standard deviation obtained from the chemical analysis were calculated. Malay rose apple juice with ginger had the highest crude protein (1.06%), crude fat (0.02%) and crude ash (0.05%) while Malay rose apple juice without ginger had the highest carbohydrate (9.46%) value. Malay rose apple jam with ginger had the highest crude protein value (1.29%), crude fat (0.15%) and crude ash (0.22%) while Malay rose apple jam without ginger had the highest carbohydrate (17.57%) value. The malay rose apple juice with ginger had the highest β-carotene (2815mcg/100g) value and vitamin E (1.31mg/100g) value while the juice without ginger had the highest vitamin C (19.54mg/100g) value. The jam with ginger had the highest vitamin E (1.24mg/100g) value while the jam without ginger had the highest β-carotene (5740mcg/100g) value and vitamin C (9.74mg/100g). All the minerals tested in the juice with ginger had higher values than the juice without ginger except for Iron. Values of the mineral composition of the jam with ginger were higher than the values for jam without ginger except for Phosphorus and Zinc. The juice without ginger had the highest DPPH inhibition level (45.93%) while the jam with ginger had the highest DPPH inhibition level (41.67%). Based on the nutrient profile of the Malay rose apple products, it appears to be good alternative for other commercial jams and can make substantial contribution to provitamin A, vitamin C and carbohydrate intake.

 








TABLE OF CONTENTS

Title page                                                                                                        i

Certification                                                                                                   ii

Dedication                                                                                                      iii

Acknowledgement                                                                                          iv

Table of contents                                                                                            v

List of tables                                                                                                   ix

List of figures                                                                                                 x

Abstract                                                                                                          xi

                                                                                                                       

CHAPTER 1

INTRODUCTION                                                                                        1

1.1         Statement of problem                                                                       4

1.2         Objectives of the study                                                                     5

1.2.1      General objective of the study                                                          5

1.2.2      Specific objectives of the study                                                        5

1.3         Significance of the study                                                                  6

 

CHAPTER 2

LITERATURE REVIEW                                                                            8

2.1          Fruits                                                                                                8

2.1.1       Fruits and vegetables as sources of vitamins, minerals and

    antioxidants                                                                                     9

2.1.1.1    Nutritional importance and contribution of fruits and

                vegetables                                                                                       9

2.1.2.      Fruit and vegetable consumption: Human health and disease

                prevention                                                                                       12

2.1.3       Possible mechanism of action of fruits and vegetables in

                human health and disease prevention                                             15

2.1.4       Factors affecting the nutritional qualities and consumption of

                fruits and vegetables                                                                       18

2.1.5        Products derived from fruits                                                           20

2.2           Fruit juice                                                                                       21

2.2.1        Selection and quality of fruits used for juice                                 22

2.2.2        The technology of juice extraction and processing                        23

2.2.3        Preparation of raw materials                                                           24

2.2.4        Extraction                                                                                       24

2.2.5        Clarification                                                                                    25

2.2.6        Pasteurization                                                                                 26

2.2.7        Concentration                                                                                 27

2.2.8       Aseptic packaging                                                                           28

2.2.9         Cooling                                                                                          29

2.2.10       Nutritional and health benefits of fruit juice                                 29

2.3            Fruit jam                                                                                        31

2.3.1         Jam Making                                                                                   33

2.3.2         Raw materials for jam manufacture                                              33

2.3.2.1      Fruits                                                                                              34

2.3.2.2      Sugar                                                                                              34

2.3.2.3      Pectin                                                                                             34

2.3.2.4      Acid                                                                                               35

2.3.2.5      End point of jam making                                                               35

2.3.2.6      Packaging                                                                                      36

2.3.2.7      Factors affecting quality of jam                                                    36

2.4            Malay rose apple (Syzygium malaccense)                                     37

2.4.1         Scientific classification of Malay Rose apple                               37

2.4.2         Origin and distribution of Malay rose apple                                 37

2.4.3         Nutritional value and composition of Malay rose apple               39

2.4.4         Uses of Malay Rose apple                                                                         40

2.4.4.1      Food uses                                                                                       40

2.4.4.2      Medicinal uses                                                                               42

2.5            Ginger (Zingiber officinale)                                                          42

2.5.1         Nutritional value and composition of ginger                                 44

 

CHAPTER 3

MATERIAL AND METHODS                                                                   45

3.1            Study design                                                                                  45

3.2            Sources of raw material                                                                 45

3.3            Selection of fruits for production of jam and juice                       45

3.3.1         Preparation of Malay Rose Apple Jam                                          45

3.3.2         Preparation of Malay Rose Apple Juice                                        48

3.4            Sensory evaluation                                                                        50

3.5            Chemical analysis                                                                          51

3.5.1         Proximate analysis                                                                         51

3.5.1.1      Moisture determination                                                                 51

3.5.1.2      Crude protein determination                                                          52

3.5.1.3      Determination of total ash                                                             53

3.5.1.4      Determination of crude fat content                                                     54

3.5.1.5      Determination of crude fibre                                                         55

3.5.1.6      Determination of carbohydrate                                                     56

3.6            Determination of minerals                                                             56

3.6.1         Mineral element extraction                                                            56

3.6.2         Determination of calcium and magnesium                                    57

3.6.3    Determination of potassium and sodium using the flame

             photometer                                                                                         58

3.6.4    Determination of zinc and iron                                                          59

3.6.5    Determination of phosphorus                                                            59

3.7       Vitamin analysis                                                                                60

3.7.1    Determination of riboflavin                                                               60

3.7.2    Determination of niacin                                                                     61

3.7.3    Determination of thiamin                                                                  62

3.7.4    Determination of vitamin C (ascorbic acid)                                      63

3.7.5    Determination of β- carotene (pro-vitamin A)                                  64

3.7.6     Determination of vitamin E                                                               65

3.8       Determination of phytochemicals/anti-nutrients                               66

3.8.1    Determination of flavonoids                                                              66

3.8.2     Phenol determination                                                                        66

3.8.3    Determination of alkaloids                                                                68

3.8.4    Determination of tannin                                                                    69

3.9       Determination of anti-oxidant                                                           70

3.9.1    Determination of 1,1-diphenyl-2-picrylhydrazyl free radical

             scavengins ability (DPPH)                                                                 70

3.10     Physicochemical analysis                                                                  70

3.10.1   Determination of pH                                                                          70

3.10.2   Determination of total soluble solids                                                 71

3.10.3  Determination of total titrable acidity                                               72

3.11     Statistical Analysis                                                                            72

 

CHAPTER 4

RESULTS AND DISCUSSION                                                                   73       

4.1       Chemical properties of malay rose apple (Syzgium

            malaccense) juices                                                                              73

4.1.1    Energy and proximate composition of malay rose apple juices            73

4.1.2    Mineral composition of malay rose apple juices                                76

4.1.3    Vitamin composition of malay rose apple juices                               79

4.1.4    Phytochemical/Anti-nutrient composition of malay rose apple

            juices                                                                                                   83

4.1.5    Antioxidant properties of malay rose apple juices                             84

4.1.6    Physicochemical properties of malay rose apple juices                     85

4.2       Sensory evaluation of the malay rose apple (Syzygium

            malaccense) juices and commercial pineapple juice                         87

4.2.1    Sensory evaluation of malay rose apple juices and commercial        87

            pineapple juice

                                                           

4.3       Chemical properties of malay rose apple (Syzgium

            malaccense) jam                                                                                 88

4.3.1    Energy and proximate composition of malay rose apple jam 88

4.3.2    Mineral composition of malay rose apple jam                                   91

4.3.3    Vitamin composition of malay rose apple jam                                   94

4.3.4    Phytochemical/Anti-nutrient composition of malay rose apple

            jam                                                                                                      97

4.3.5    Antioxidant properties of malay rose apple jam                                98

4.3.6    Physicochemical properties of malay rose apple jam                        99

4.4       Sensory evaluation of the malay rose apple (Syzygium

            malaccense) jam and commercial pineapple jam                               100

4.4.1    Sensory evaluation of malay rose apple jam and commercial

            pineapple jam                                                                                     100

 

CHAPTER 5

CONCLUSION                                                                                             103

5.1      Conclusion                                                                                           103

5.2      Recommendation                                                                                104

REFERENCES                                                                                               106

Appendix I                                                                                                      120

Appendix II                                                                                                     122

 


 

LIST OF TABLES

Table 2.1:        Nutritive value of malay rose apple per 100g of edible

                        portion                                                                                     40

Table 2.2         Nutritive value of ginger per 100g (3.5 oz)                            44

Table 3.1         Recipe for jam preparation                                                     46

Table 3.2         Recipe for juice preparation                                                   48

Table 4.1         Energy and proximate composition of malay rose

                        apple juices                                                                               75

Table 4.2         Mineral composition of malay rose apple juices                    78

Table 4.3         Vitamin composition of malay rose apple juices                   81

Table 4.4         Phytochemical/Anti-nutrient composition of malay

                        rose apple juices                                                                     83

Table 4.5         Antioxidant properties of malay rose apple juices                 84

Table 4.6         Physicochemical properties of malay rose apple

                        juices                                                                                       86

Table 4.7         Sensory evaluation of the malay rose apple (Syzygium

                        malaccense) juices and commercial pineapple juice             88

Table 4.8         Energy and proximate composition of malay rose apple

                        jam                                                                                            89

Table 4.9         Mineral composition of malay rose apple jam                       93

Table 4.10       Vitamin composition of malay rose apple jam                       95

Table 4.11       Phytochemical/Anti-nutrient composition of malay rose

                        apple jam                                                                                97

Table 4.12       Antioxidant properties of malay rose apple jam                    98

Table 4.13       Physicochemical properties of malay rose apple jam             99

Table 4.14       Sensory evaluation of the malay rose apple (Syzygium

                        malaccense) jam and commercial pineapple jam                   101

 





LIST OF FIGURES

Figure 3.1        Flow chart for malay rose apple jam                                      47

Figure 3.2        Flow chart for malay rose apple and ginger jam                    47

Figure 3.3        Flow chart for malay rose apple juice                                    49

Figure 3.4        Flow chart for malay rose apple and ginger juice                  49

 

 

 

 

 


 

 

 

 

CHAPTER 1

INTRODUCTION

Malnutrition is a major public health problem throughout the developing world, particularly in Southern Asia and sub-Saharan Africa (Food and Agricultural Organization, 2001; World Health Organization, 2004). Low fruit and vegetable intake have been identified as one of the main contributors of micronutrients in developing countries. Their intakes are still grossly inadequate both in developed and developing countries (International Agency for Research on Cancer (IARC), 2003). Diets of population in Nigeria are frequently deficient in macronutrient (protein, carbohydrate, and fat, leading to protein energy malnutrition) and micronutrients (electrolytes, minerals and vitamins, leading to specific micronutrient deficiencies or both) (Millward and Jackson, 2004).

Plant foods shows the largest segment of dietary diversity that offers useful perspectives on a number of issues of contemporary scientific and public health importance including micronutrient deficiency and bioavailability, nutrition and disease, medicinal and functional activities (Johns, 2003; Popkin, 2002; Kant et al., 1995). Fruits as members of plant foods are generally known for their rich micronutrient constituents (Shiundu, 2002).            

Most fruits are perishable and as a result, cannot be stored for a very long period while some are seasonal and cannot be available when they are not in season and now most fruits are processed into juices, syrups, jams, jellies so as to ensure their availability all year round. In Nigeria, the availability of fruits is short lived due to their seasonal and highly perishable nature (Akubor and Ogbalu, 2005).

Fruit juices are beverages derived from whole fruits: apple, orange, pineapple, grapes and more exotic varieties, such beverages exhibit different characteristics ranging from natural cloudy products to fully classified juices (Murano, 2003). In many countries the differences between fruit juices and nectars is considered necessary to avoid confusion between fruit juices and lime containing beverages such as squashes and carbonate. In European Economic Community, a directive defines fruit juice as juice obtained from fruit by mechanical process, fermentable but unfermented having the characteristics colour and flavour typical of the fruit from which it comes (Murano, 2003).

Fruit jam is an example of fruit preserve usually made from pulp and juice of one fruit (whole fruit). It can be defined as cooked and gelled fruit purses packaged for long term storage which is normally used as bread spread, filling and food jellies. The preparation of fruit jam traditionally involves the use of pectin as a gelling agent, although sugar and citric acid may be added as well (Pattern, 2001).

Malay rose apple (Syzygium malaccense) is one of the lesser known, seasonal and underutilised fruit found in the tropics and in Nigeria ecosystem. There are different varieties from the Syzyium family which are Syzygium samarangense (Bell apple), Syzygium aquem (Water apple) and Syzygium malaccense (Malay rose apple).Malay rose apple has been cultivated since pre-historic times has naturalized in many parts of the tropics particularly in Malaysia (Merr and Perry, 2007). Ripe fruits are rich in vitamin A, vitamin B complex and Vitamin C (Field Manual for Extension Workers and Farmers, Southampton Centre for Underutilized Crops (FMEWF), 2006). Due to high levels of vitamins, malay rose apple supplements other staple fruits in times of scarcity in some region (International Centre for Underutilized Crops (ICUC), 2003). Malay rose apples are often cooked with acid fruits to the benefit of both. They are sometimes made into sauces or preserves. The slightly unripe fruits are used for making juice, wine, jelly and pickles. Jam can be prepared from malay rose apple by stewing the flesh with brown sugar and ginger (Morton, 1987). However, in Nigeria, most of the malay rose apple are wasted during the fruiting season and have not been utilized to produce processed products. Production of ready to serve (RTS) beverages from fruit pulp of some underutilized fruit plants has helped to reduce these fruits being wasted during fruiting season.

The sole aim of nutritionists, food scientist and biochemist is to explore the various sources in which the different nutrient could be obtained especially from sources which abound in our immediate environment. This has led to various researches to produce food products and determine the various compositions of sampled fruits which are less commonly eaten in our society. Research and information on Malay rose apple is few and very scanty and there is need to advocate for the regular consumption of food products developed from this fruit by finding ways to make it available in easier to prepare form just as in juice and jam.

This research work is aimed at the production of food products (juice and jam) from the pulp of malay rose apple as well as analyzing the food products to establish their chemical composition and general acceptability in order to investigate the possibility of promoting their usage as food for human consumption.


1.1       STATEMENT OF PROBLEM

Low fruits and vegetable intake have been identified as one of the main contributors of micronutrients deficiency in developing countries. Their intakes are still grossly inadequate both in developed and developing countries (IARC, 2003).  Fruits are good sources of calories and insufficient calorie consumption often goes hand-in-hand with micronutrient deficiency (FAO, 2004). Nigeria is still faced with the challenge of meeting the basic food needs of its population (Otacha, 2013) as well as been faced with the problem of  micronutrient deficiency due to ignorance arising from not including fruits and vegetables in their diets (United Children Emergency Fund (UNICEF), 2004) which can lead to a wide range of diseases. Underutilized foods such as the malay rose apple could be used to meet the world food security demands starting from Nigeria when properly processed and prepared for consumption. The inability of people to consume fruits in adequate amount is also due to lack of good quality variety and uneven distribution of these fruits across different parts of the World (Ubbaonu et al., 2005). In Nigeria, different fruits are grown of which may fail to reach the market due to spoilage, mechanical damages and over ripening. Therefore there is the need for proper utilization of fruits and vegetables so as to make available always and even during off seasons by processing them into food products. There is also less awareness on the nutritional value of most fruits and vegetables which has limited its utilization in the production of food products and also led to its wastage.

It is therefore the objective of this study to evaluate the products (juice and jam) developed from Malay rose apple (Syzygium malaccense).


1.2       OBJECTIVES OF THE STUDY

1.2.1    General objective of the study

The general objective of this study is to evaluate the chemical composition, anti-oxidant and physico-chemical properties of products (juice and jam) developed from malay rose apple (Syzygium malaccense).

1.2.2    Specific objectives of the study

The specific objectives are to;

i.      develop jam and juice from malay rose apple.

ii.     evaluate the sensory properties of the food products (jam and juice) produced from malay rose apple.

iii.   evaluate the chemical composition of juice and jam produced from malay rose apple.

iv.   evaluate the anti-oxidant activity of the juice and jam made from malay rose apple.

v.     evaluate the physico-chemical properties of the juice and jam made from malay rose apple


1.3       SIGNIFICANCE OF THE STUDY

This research work will be of benefit to the entire populace by providing them with the information on the nutrient potentials of malay rose apple products (juice and jam) thereby encouraging individuals to consume more of it as well as reducing its wastage during fruiting season. This study will also help to create more job opportunities for individuals especially the youths by encouraging them to cultivate, produce and sell the fruits and by this the economy of the country will be improved.

Furthermore, this study will be of help to dietitians in the utilization of malay rose apple and its products in formulating and planning of diet of patients thereby encouraging diversification of diet (elimination of monotonous diet) which in turn helps to reduce the problem of food insecurity, hunger and malnutrition in Nigeria. This study will provide nutritionist and food scientist with information on the nutrient composition and sensory properties of the products developed from malay rose apple thus enhancing the utilization and consumption of the fruit and its product to promote good health as well as expanding the market for malay rose apple products.

The information from the study will also be useful to nutrition educators, doctors, nurses, and other health workers in order to advise, enlighten and educate the society on malay rose apple, its benefits to human health as well as encouraging them to consume the fruit and its products.

This study will encourage the agricultural sector to cultivate more malay rose apple trees from which the fruit will be obtained and utilized by the food industry in providing juice and jam for human consumption and making it available during off seasons. The products made by the food industry will also add variety to diets of Nigerians.

 

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