SOME ASPECTS OF THE PHYSICO-CHEMISTRY AND BACTERIOLOGICAL ANALYSIS OF IBINI STREAM IN AMAWOM, IKWUANO L.G.A, ABIA STATE, NIGERIA

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ABSTRACT

Some aspects of the physico- chemical characteristics and bacteriological analysis of Ibini Stream were investigated from January to December 2015. Four stations were studied from upstream to downstream using standard methods. A total of fifteen physico-chemical characteristics were examined with the following findings: Air and water temperatures ranged between 25.5oC and 29.6oC and 25.0oC to 29.0oC. The pH and alkalinity values ranged from 5.0 to 7.97 and 8.0mgl-1 to 202mgl-1. Conductivity ranged from 65.1µScm-1 to 422.4µScm-1 and Total dissolved solids from 40mgl-1 to 298mgl-1. Dissolved oxygen ranged from 1.1mgl-1 to 7.8mgl-1 while biochemical oxygen demand ranged from 0.4mgl-1 to 6.5mgl-1. Potassium ranged from 1.0mgl-1 to 9.04mgl-1. Calcium and magnesium ranged from 3.8mgl-1 to 40.1mgl-1 and 40mgl-1 and 298mgl-1.  Iron ranged from 0.04mgl-1 to 38.1mgl-1.  Copper ranged from 0.01mgl-1 to 1.42mgl-1 while zinc ranged from 0.01mgl-1 to 0.04mgl-1. All the parameters exhibited clear seasonal variations. The statistical analysis of the results of some physicochemical parameters was done using analysis of variance (ANOVA) and Post Hoc Duncan test. ANOVA showed a significant difference (p < 0.01, 0.001) in the values of pH, and BOD5, among the stations. A total of fifteen bacterial species were isolated from the water. These were Enterobacter aerogenesProteus vulgarisEscherichia coliStaphylococcus epidermidisS. aureusPseudomonas aeruginosaSphaerotilus natansErwinia amylovoraBacillus licheniformisShigella dysenteriaeS. sonnei, Klebsiella pneumoniaeSerratia marcescensSalmonella enteritidis and Yersinia enterocolitica. The total bacterial count of the water of the river ranged from 1.7 x 103 to 2.15 x 104 cfu/ml. The health risks or coliforms in this stream is of serious concern as the water from this river is being used for domestic purposes and recreational activities like swimming while the bank of the river is used for agricultural purpose of planting of vegetables and fruits and in some instances planting of rice in the shallow areas in the river. The biological health risks include gastroenteritis, diarrhea, pneumonia etc resulting from consumption of water from this Stream.






TABLE OF CONTENTS

Title Page                                                                                                                    i

Declaration                                                                                                                  ii

Certification                                                                                                                iii

Dedication                                                                                                                  iv

Acknowledgements                                                                                                    v

Table of Contents                                                                                                       vi

List of Tables                                                                                                              ix

List of Figures                                                                                                             x

List of Plates                                                                                                               xi

Abstract                                                                                                                      xii

 

CHAPTER 1: INTRODUCTION                                                                          1

1.1       Background Information                                                                                1

1.2       Statement of the Problem                                                                               4

1.3       Justification                                                                                                     5

1.4       Aim and Objectives                                                                                        5

 

CHAPTER 2: LITERATURE REVIEW                                                              6

2.1       Physico-Chemistry                                                                                          6

2.2       Bacteriology                                                                                                    9

 

CHAPTER 3: MATERIALS AND METHODS                                                   11

 

3.1       Description of Study Area                                                                              11

3.1.1    Sampling stations                                                                                            11

3.2       Methods                                                                                                          18

3.2.1    Sterilization of glassware and other materials                                    18

3.2.2    Preparation of culture media                                                                           18

3.2.3    Determination of physicochemical characteristics                                          18

3.2.4      Physical measurements                                                                                 18

3.2.4.1   Temperature determination                                                                           18

3.2.4.2   pH determination                                                                                          19

3.2.5      Chemical measurements                                                                                19

3.2.5.1   Total dissolved solids (TDS) determination                                                 19

3.2.5.2   Total hardness determination                                                                        19

3.2.5.3   Alkalinity determination                                                                               20

3.2.5.4   Electrical conductivity determination                                                           20

3.2.5.5    Dissolved oxygen determination                                                                 20

3.2.5.6    Biological oxygen demand at day 5 (BOD5)                                               21

3.2.5.7    Potassium determination                                                                              21

3.2.5.8   Calcium determination                                                                                  21

3.2.5.9   Magnesium determination                                                                            22

3.2.5.10  Trace and heavy metals                                                                                22

3.2.6       Bacteriological analysis                                                                                23

3.2.6.1    Test for coliform bacteria                                                                             23

3.2.6.1.1  Presumptive coliform test                                                                           23

3.2.6.1.2 Confirmatory test                                                                                         24

3.2.6.1.3 Completed test                                                                                             24

3.2.6.2    Isolation of bacteria from water                                                                  24

3.2.6.3    Purification of bacterial isolates                                                                   24

3.2.6.4    Characterization and identification of bacterial isolates                              25

 

3.2.6.5    Colonial morphology                                                                                   25

3.2.6.6    Gram staining                                                                                               25

3.2.6.7     Motility test                                                                                                25

3.2.6.8     Biochemical tests                                                                                        26

3.2.6.8.1  Coagulase test                                                                                             26

3.2.6.9     Characterization and identification of bacterial isolates                             26

3.2.6.10   Statistical analysis treatment of data                                                          26

CHAPTER 4: RESULTS AND DISCUSSION                                                    27

4.1          Results                                                                                                         27

4.1.1       Air temperature                                                                                            27

4.1.2       Water temperature                                                                                       27

4.1.3       pH                                                                                                                31

4.1.4       Conductivity                                                                                                            33

4.1.5       Alkalinity                                                                                                     35

4.1.6       Total dissolved solids                                                                                  37

4.1.7       Total hardness                                                                                              39

4.1.8       Dissolved oxygen                                                                                        41

4.1.9       Biological oxygen demand on day 5 (BOD5)                                              43

4.1.10     Cations                                                                                                         45

4.1.10.1  Calcium                                                                                                        45

4.1.10.2  Magnesium                                                                                                   47

4.1.10.2  Potassium                                                                                                     49

4.1.11     Trace and heavy metals of water samples from Ibini stream                       51

4.1.12     Bacteriological analysis                                                                                56

4.1.12.1  Coliform counts                                                                                           56

4.1.12.2  Identification of bacterial isolates                                                               58

4.1.12.3  Bacterial counts of Ibini stream                                                                   58

4.2          Discussion                                                                                                    62

CHAPTER 5: CONCLUSION AND RECOMMENDATIONS                         72

5.1       Conclusion                                                                                                     72

5.2       Recommendations                                                                                         72

  References                                                                                                    73

  Appendix





LIST OF TABLES

TABLE                                                                                                                    PAGE

4.1:      Summary of physico-chemical parameters of Ibini stream (with range in

            parenthesis) compared with SON, WHO, EEC & USEPA water

standards                                                                                                         28

 

4.2:      Post hoc (Duncan) results showing station-station relationship of Ibini

stream in 2015                                                                                                 55

 

4.3:      Bacterial frequency distribution of water samples of Ibini stream

(January- December 2015)                                                                              59

 

4.4:      Total bacterial counts of water samples of station points

(January – December 2015).                                                                           61

 

 

 

 

LIST OF FIGURES

FIGURE                                                                                                                 PAGE

1:         Map of study area (Ibini stream)                                                                    13

2:         The spatial and temporal variations of air temperature in Ibini stream           29

3:         Spatial and temporal variations of  water temperature of Ibini stream           30

4:         pH values of water samples of Ibini stream in 2015                                       32

5:         Conductivity values of water samples of Ibini stream in 2015                      34

6:         Alkalinity values of water samples of Ibini stream in 2015                            36

7:         TDS values of water samples of Ibini stream in 2015                                    38

8:         Total hardness (mg/l) values of water samples of Ibini stream in 2015          40

9:         DO (mg/l) values of water samples of Ibini stream in 2015                           42

10:       BOD5 (mg/l) values of water samples of Ibini stream in 2015                       44

11:       Calcium values of water samples of Ibini stream in 2015                              46

12:       Magnesium values of water samples of Ibini stream in 2015                         48

13:       Potassium values of water samples of Ibini stream in 2015                           50

14:       Copper (mg/l) values of water samples of Ibini stream in 2015                     52

15:       Iron (mg/l) values of water samples of Ibini stream in 2015                          53

16:       Zn (mg/l) values of water samples of Ibini stream in 2015                             54

17:       Most probable number (MPN) values of water samples Ibini stream in

2015                                                                                                                57

18:       Bacterial frequency distribution of water samples of Ibini stream

(January- December 2015)                                                                              60

 

 

 

LIST OF PLATES

PLATE                                                                                                                    PAGE

1:                     Station 1 in Ibini stream in Amawom area                                         14

2:                     Station 2 in Ibini stream in Amawom area                                   15

3:                     Station 3 in Ibini stream in Amawom area                                         16

4:                     Station 4 in Ibini stream in Amawom area                                         17

 

 

 

 

 


CHAPTER 1

INTRODUCTION


1.1       BACKGROUND INFORMATION

As the world is ushered into the modern era of civilization, water and its management will continue to be a major issue, which will definitely have profound impact on our lives and that of our planet Earth than before (Goudie, 2013). All living organisms on the earth need water for their survival and growth. As of now only earth is the planet having about 70% of water (Basavaraja et al., 2011).  According to Julien (2010), society uses water to generate and sustain economic growth and prosperity, through activities such as farming, commercial fishing, energy production, manufacturing, transport and tourism while Mohanty (2006) described water as the Elixir of life and a wonderful gift. Therefore, it is important to make water available in good quality and quantity, at the appropriate place and time. Though water covers 3/4th of the planet earth, the implication is that water is readily available, yet it is one of the most earth’s prized resources (Talling, 2005). The ensuring of good quality drinking water is a basic factor in guaranteeing public health, the protection of the environment and sustainable development (Ranjini et al., 2010).

 

Water pollution is of grave consequence because both terrestrial and aquatic life may be poisoned; it may cause disease due to the presence of some hazardous substances, may distort the water quality, add odours and significantly, hinder economic activities (Mason, 2002). Any alteration in the physical, chemical and biological properties of any water due to discharge of any liquid, gaseous or solid substances that is likely to create detrimental or injurious effect to aquatic life and consequently public health, could be termed water pollution (Pandey and Shukla, 2005). Additionally, several human activities that may result to water pollution include the following, agriculture, irrigation, urbanization, mining, fire, and industrialization (Goudie, 2013). These activities have been documented to have impacted negatively in some specified Nigerian surface waters (Izonfuo and Bariweni, 2001). Amongst the serious environmental problems are waste accumulation and lack of adequate and safe water supply (Buor, 2003).

In Nigeria, high priority is given to fresh water resources due to growing concern of the increasing stress on water supplies caused by poor use patterns affecting both water quality and quantity. Though water pollution is an old phenomenon, the rate of industrialization and consequently urbanization has exacerbated its effect on the environment. This is because, the process of urbanization has considerable hydrological impact both in terms of controlling rate of erosion, delivery of pollutants to rivers, and in terms of influencing the nature of runoff and other hydrological characteristics (Goudie, 2013).

 

Water quality data include variables that have significant impact on designated water use such as chemical and bacteriological characteristics, those affecting the taste and odour and those with indirect effect (WHO, 2004). Microorganisms are widely distributed in nature, their composition, abundance and diversity may be used as an indicator for the suitability of water. The quality of water influence the health status of any populace, hence, analysis of for physical, biological and chemical properties including trace element contents are very important for public health studies (Shalom et al., 2011). The use of bacteria as water quality indicators can be viewed in two ways, first, the presence of such bacteria can be taken as an indication of faecal contamination of the water and thus as a signal to determine why such contamination is present, how serious it is and what steps can be taken to eliminate it; second, their presence can be taken as an indication of the potential danger of health risks that faecal contamination posses (Eze and Chigbu, 2015). A wide range of pathogenic microorganisms can be transmitted to humans via water contaminated with faecal material. These include enteropathogenic agents such as salmonellas, shigellas, enteroviruses, and multicellular parasites as well as opportunistic pathogens like Pseudomonas sp, Klebsiella and Vibrio spp (Talling, 2005).

 

The physical and chemical characteristics of water bodies affect the species composition, abundance, productivity, and physiological conditions of aquatic organisms (Talling, 2005). The physico-chemical factor also influences the distribution and feeding pattern of aquatic organisms (Umeham et al., 2012).

Water temperature has a double influence on aquatic organisms. Aquatic organisms are tolerant at certain absolute values and ranges of temperature beyond which they cannot function. Crillet and Quentin (2006) noted that water temperature influences the rate of metabolism, spawning and embryo development.

The effect of pH on the chemical and biological properties of liquids makes its determination very important. It is one of the most important parameters in water chemistry and is defined as the negative logarithm of the hydrogen ion (H­+) concentration.

 

Conductivity (specific conductance) is the numerical expression of the waters ability to conduct electric current. According to Umeham & Etusim (2004), conductivity of water is used to estimate the concentration of dissolved organic matter, which in turn is related to water fertility.

Transparency has an opposite correlation with turbidity, rainfall, water level and the periods of minimum transparency usually correspond with periods of high level of plankton biomass (Umeham et al., 2012).

 

Hard drinking water may have moderate health benefits, but can pose serious problems in industrial settings, where water hardness is monitored to avoid costly breakdowns in boilers, cooling towers, and other equipments that handle water (Kolo, 2007).

 

Alkalinity is the water’s capacity to resist changes in pH that would make the water more acidic. Alkalinity of natural water is as a result of bi-carbonate ions expressed in terms of calcium carbonate (CaCo3). It is caused by or attributed to the presence of bi-carbonate, carbonate and hydroxide, less frequently by silicates and phosphate ions (Umeham and Elekwa, 2005). High alkalinity is good to have in our drinking water because it keeps the water safe for us to drink. Alkalinity is basically minerals in the water that help neutralize the water we drink (Mohanty, 2006).

Dissolve oxygen in water is a very important parameter in water analysis and it serves as an indicator of physical, chemical and biological activities of the water body. The two main sources of dissolve oxygen are diffusion of oxygen from air and photosynthetic activity. Diffusion of oxygen from air into water depends on the solubility of oxygen, and is influenced by many factors like water movement, temperature, salinity, etc. Oxygen is considered to be the major limiting factor in water bodies with organic materials.

Biochemical oxygen Demand (BOD) is the amount of oxygen required by micro-organisms for stabilizing biologically decomposable organic matter (Carbonaceous) in water under aerobic conditions. The test is used to determine the pollution load of wastewater, the degree of pollution and the efficiency of wastewater treatment methods. High levels of Bio-chemical oxygen demand (BOD) indicate the presence of oxygen demanding wastes (Abowei and George, 2009).

 

1.2     STATEMENT OF THE PROBLEM

Water quality has a direct impact on public health. More than 80% of deaths are caused due to water borne diseases and heavy metals (WHO, 2011). The water supply in Amawom Oboro, Ikwuano L.G.A is insufficient as per demand to consumers. This is exacerbated due to the fact that many students of Michael Okpara University of Agriculture, Umudike reside in private hostels in the area. Consequently, people of Amawom have shown increasing dependence on water from Ibini stream for domestic purposes like drinking, washing, cooking, bathing, etc.

 

1.3       JUSTIFICATION

1.         This research is justified since it is a preliminary study; it will serve as a baseline study thereby contributing to the database of rivers and streams of South Eastern Nigeria.

2.         The stream serves good number of purposes to the citizenry (washing of industrial wares by nearby mechanics, laundry and other culinary purposes), this research will provide scientific base for ascertaining the safety of the water usage.

3.         Aquatic ecosystems are increasingly threatened by human population growth and development. Therefore, evaluation of microbial pollution sources and levels are essential for proper monitoring of water quality threats.

 

1.4       AIM AND OBJECTIVES

The aim of this study is to carry out physico-chemical and bacteriological assessment of Ibini stream.

The objectives are:

1.                  To evaluate aspects of the physico-chemistry of Ibini stream and compare with national and international standards.

2.                  To evaluate the seasonal and anthropogenic effects on the physico-chemistry of Ibini stream.

3.                  To evaluate the composition, distribution and abundance of waterborne bacteria of medical importance in Ibini stream.

4.                  To relate the physico-chemistry to the bacteriology of Ibini stream.



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