ISOLATION AND CHARACTERIZATION OF ANTIFUNGAL METABOLITES OF BACILLUS SPECIES

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ABSTRACT


A major characteristic shared among Bacillus strains is the ability to produce a wide range of antimicrobial compounds that are active against bacteria and fungi. Bacillus species was isolated from soil samples collected from refuse dump site. The bacterial isolate exhibited antagonistic activity when cultured with fungi on Potato Dextrose agar plates. Antifungal metabolites produced by Bacillus species in Potato Dextrose Broth were extracted from fluid culture supernatant by evaporation with ethyl acetate giving a yield of 0.21g dry metabolites from 1 litre fluid culture on average. The antifungal metabolites inhibited mycelial growth of fungal species – AspergillusRhizopus and Fusarium. The inhibition zones were observed for more than four days and there was no observed change in the size of the zones. The antifungal metabolites were subjected to different pH levels and were active and stable over a wide range of pH (2-10). They were exposed to very high temperatures and were stable and remained active after sterilization at 121oC for 15min. The metabolites were soluble in water and organic solvents like ethanol and were resistant to denaturation by enzymes. The effect of these antifungal metabolites against postharvest fungal pathogens under various circumstances suggest that they could be a potent source of antifungal not just for postharvest fungal pathogens but human and animal fungal pathogens alike.





TABLE OF CONTENTS

Title page                                                                                                                                i

Certification                                                                                                                            ii

Dedication                                                                                                                              iii

Acknowledgement                                                                                                                  iv

Table of Contents                                                                                                                   v

List of Tables                                                                                                                          ix

List of Figures                                                                                                                         x

Abstract                                                                                                                                  xi

CHAPTER ONE

INTRODUCTION                                                                                                                1

1.1                 Introduction                                                                                                              1

1.2                 Objectives                                                                                                                  2

CHAPTER TWO

LITERATURE REVIEW                                                                                                   3

2.1         Bacterial Metabolites                                                                                                3

2.1.1      Antimicrobial properties of bacterial metabolites                                                     5

2.1.2      Bioactivity of Microbial secondary metabolites                                                       5

2.2         The Bacillus species                                                                                                  6

2.2.1      History of Bacillus species                                                                                        7

2.2.2      Taxonomy of Bacillus species                                                                                   12

2.2.3       Life cycle of Bacillus species                                                                                   14

2.3          Catabolite Repression                                                                                              17

2.4          Resistance of Spores                                                                                                19

2.5          Production of Antibiotics                                                                                        21

CHAPTER THREE

MATERIALS AND METHODS

3.1          Sample Collection                                                                                                    26

3.2          Sterilization of Materials                                                                                          26

3.3          Media Preparation                                                                                                    26

3.4          Isolation of Organism                                                                                              26

3.4.1       Cultural characteristics on various media                                                                27

3.4.1.1    Nutrient agar                                                                                                            27

3.4.1.2    Potato dextrose agar                                                                                                27

3.4.1.3    Gram staining                                                                                                           27

3.5           Test for Antifungal Activity                                                                                   28

3.6            Further Identification Tests                                                                                   28

3.6.1         Motility                                                                                                                  28

3.6.2         Catalase Test                                                                                                          28

3.6.3          Indole Test                                                                                                            29

3.6.4          Hydrolysis of starch                                                                                              29

3.6.5          Methyl Red Test                                                                                                   29

3.6.6          Voges Proskauer                                                                                                   30

3.6.7          Citrate utilization Test                                                                                          30

3.6.8          Sugar fermentation test                                                                                         31

3.7             Extraction of Antifungal Metabolites                                                                   31

3.8             Characterization of Antifungal Metabolites                                                         32

3.8.1          Antifungal Activity                                                                                              32

3.8.2         Thermal Stability                                                                                                    32

3.8.3         pH Stability                                                                                                            32

3.8.4         Susceptibility to denaturation by enzymes                                                            32

3.8.5         Solubility in organic solvents                                                                                 33

CHAPTER FOUR

RESULTS

4.1          Identification of the bacterial isolate                                                                       34

4.2          Identification of fungal species                                                                               34

4.3          Extraction of antifungal metabolites                                                                       34

4.4          Antifungal activity of the extracted metabolites                                                     34

4.5          pH stability of the extracted metabolites                                                                 35

4.6          Thermal stability of the extracted metabolites                                                         35

4.7          Susceptibility to denaturation by enzymes and solubility in organic solvents         36

CHAPTER FIVE

DISCUSSION, CONCLUSION AND RECOMMENDATION                                      44

5.1          Discussion                                                                                                                44

5.2          Conclusion                                                                                                               46

5.3          Recommendations                                                                                                   47

References                                                                                                                             48

 

 

 LIST OF TABLES

Table                                                  Title                                                                            Page   

2.1        Origins of isolates of Bacillus species                                                             10

2.2        Some Bacillus antibiotics                                                                                            24

4.1       Cultural and biochemical characteristics of the isolated antifungal-producing

            bacteria                                                                                                                        37

2.3              Cultural and morphological characteristics of the fungal species                               38

2.4              Inhibition of mycelial growth of some fungal species by antifungal

metabolites produced by Bacillus species                                                                   39

2.5              Inhibition of mycelial growth of Rhizopus by antifungal metabolites of

Bacillus species treated at different pH values                                                           40

2.6              Inhibition of mycelial growth of Aspergillus by antifungal metabolites of

Bacillus species treated at different pH values                                                           41

2.7              Inhibition of mycelial growth of Fusarium by antifungal metabolites of

Bacillus species treated at different pH values                                                           42

2.8              Inhibition of mycelial growth by heat treated (121oC/15min) antifungal

Metabolites of Bacillus species                                                                                   43

 

 

 

 

LIST OF FIGURES

Figure                                                 Title                                                                Page

2.1      B. megaterium sporeforming cells as seen in the phase contrast or

           in the interference contrast microscope                                                             9

2.9        Cycle of germination, outgrowth and sporulation of a typical spore-

forming bacterium                                                                                           16

 

 

 


 

 

 

CHAPTER ONE

INTRODUCTION


1.1       Introduction

Bacteria that show inhibitory action against fungi can contribute immensely to the prevention of plant diseases and post-harvest spoilage hence serving as alternative to chemical pesticides and their metabolites as preservatives (Walsh et al., 2001). The discovery of novel, non-antibiotic small molecule pharmaceuticals or product candidates through screening microbial secondary metabolites is an expanding activity throughout the pharmaceutical industry and one that is becoming increasingly fruitful. There is widespread acceptance that microorganisms are a virtually unlimited source of novel structures with many potential therapeutic applications. Soil-borne bacteria, especially Bacillus species, have been recognized for their role in plant health and soil fertility. Soil and rhizosphere have frequently been used as model environment for screening putative agents for use in biological control of soil-borne plant pathogens.

Bacillus sp., form endospores and can tolerate extreme pH, temperature and osmotic conditions; therefore they offer several advantages over other organisms. Bacillus sp. was found to colonize the root surface, increase plant growth and cause lysis of fungal mycelia (Turner and Backman, 1991). They are regarded as safe biological agents and their potential is considered high. As bacteria their antagonistic effect is assumed to be as a result of the production of antifungal antibiotics (Korzybski et al., 1978).

Biosynthesis of antibiotics from microorganisms is often regulated by nutritional and environmental factors. It has been reported that antimicrobial substances produced by bacterial species were greatly influenced by variation of carbon sources. Several abiotic factors such as pH and temperature have been identified as having an influence on antibiotic production from bacterial (El Banna, 2006; Raaijmakers et al., 2002). Antifungal peptides produced by Bacillus species include mycobacillins, surfactins, mycosubtilins and fungistatins. The Bacillusspecies can produce a wide range of other metabolites including chitinases, and other cell wall-degrading enzymes, volatiles and compounds that elicit plant resistance mechanisms (Sadfi, 2001). Volatile metabolites produced from Bacillus species have been reported to inhibit mycelia growth of Fusarium oxysporum with the highest effect on reduction of Fusarium wilt of onion (Sharifi and Ramezani, 2003). Ryu et al., (2004) reported on promotion of growth and induction of systemic resistance (ISR) response in Arabidopsis thaliana against Erwinia carotovora sub sp. carotovora by volatile substance (vs) (acetylbutanediol and acetoin, same as the present purified compounds) from Bacillus amyloliquefaciens isolate IN937a and Bacillus subtilis isolate GB03. Therefore, volatile-substance – producing bacteria can used as biocontrol agents for protection against microbial plant diseases.

The present study was aimed at isolation of potential antagonistic soil microorganisms and extraction of antifungal components. Analysis of their characteristics, as well as their effects on growth against tested pathogenic fungi was conducted.


1.2       OBJECTIVES

The objectives of this work are

·         To isolate Bacillus species capable of producing antifungal metabolites

·         To identify the characteristics of these metabolites

·         To check the antifungal activity of the metabolites

 

 

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