PHYSICO-CHEMICAL ANALYSIS OF HONEY, PHYTOCHEMICAL ANALYSIS OF CINNAMON BARK POWDER EXTRACTS AND EVALUATION OF THEIR ANTIBACTERIAL ACTIVITIES AGAINST SELECTED RESPIRATORY TRACT BACTERIAL ISOLATES

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ABSTRACT


This work was carried out to determine the physicochemical analysis of honey, phytochemical analysis of cinnamon bark powder and to examine their antibacterial activity against isolated bacteria concerned with respiratory tract infections (RTI), which are; StaphylococcusaureusEscherichiacoli and Pseudomonasaeruginosa, isolated from sputum and throat swab specimens. The agar well diffusion method was employed for both honey and the two cinnamon bark powder extracts using nutrient agar and the inhibition zones around the six wells containing different concentrations of the samples (ranging from 3.125%-100%) were measured. Significant antibacterial activity of honey was observed against Staphylococcus aureus with a least zone of inhibition of 20mm at 6.25% concentration and a maximum inhibition zone of 45mm at 100% concentration. Also against Pseudomonas aeruginosa with a least inhibition zone of 15mm at 12.5% concentration and maximum inhibition zone of 24mm at 100% concentration and lastly against Escherichia coli with a least inhibition zone of 15mm at 3.125% concentration and maximum inhibition zone of 35mm at 100% concentration. The Minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of the honey sample was further determined, giving values of 12.5% concentration (MIC) and 25% (MBC) for Staphylococcus aureus, 25% (MIC) and 25% (MBC) for Escherichia coli and 25% (MIC) and 50% (MBC) for Pseudomonas aeruginosa. Significant antibacterial activity of ethanol extract of cinnamon bark powder was observed against Staphylococcusaureus with least inhibition zone of 10mm at 3.125% concentration and maximum inhibition zone of 22mm at 100% concentration, against Escherichiacoli with least inhibition zone of 13mm at 12.5% concentration and maximum inhibition zone of 20mm at 100% concentration but Pseudomonasaeruginosa was completely resistant. The test organisms were all resistant to aqueous extraction except that Staphylococcusaureus was susceptible by 8mm at 100% concentration only. Synergistic test using the double disk diffusion method and agar well diffusion technique was carried out. There was no synergistic effect of honey and cinnamon bark powder extracts in this study, but antagonistic effect. More effective research work is recommended for the synergy, to checkmate reviews encouraging the intake of honey and cinnamon powder together against respiratory problems.







TABLE OF CONTENTS

TITLE PAGE                                                                                                                                                          i

CERTIFICATION PAGE                                                                                                          ii

DEDICATION                                                                                                                          iii

ACKNOWLEDGEMENTS                                                                                                       iv

TABLE OF CONTENTS                                                                                                        v-ix

LIST OF TABLES                                                                                                                      x

ABSTRACT                                                                                                                              xi

 

CHAPTER ONE

1.0         Introduction                                                                                                                     1

1.1         Background of the Study                                                                                               2

1.2        Statement of Research Problem                                                                                      3

1.3        Aim of the Study                                                                                                            3

1.4        Specific Objectives                                                                                                        3

 

CHAPTER TWO

2.0          Literature Review                                                                                                           5

2.1          Honey                                                                                                                           5

2.1.1       Ancient History of Honey                                                                                              5

2.1.2       Properties of Honey                                                                                                      6

2.1.2.1    Granulation Tendency                                                                                                    6

2.1.2.2    Tendency to Absorb Moisture                                                                                        7

2.1.2.3    Viscosity                                                                                                                       7

2.1.2.4    Food Value                                                                                                                                                7

2.1.3       Antimicrobial Properties                                                                                               8

2.1.3.1    Osmolarity                                                                                                                   8

2.1.3.2     Low Water Activity and pH                                                                                           8

2.1.4        Composition of Honey                                                                                                 9

2.1.4.1     Water Content                                                                                                              9

2.1.4.2      Sugars                                                                                                                         9

2.1.4.3     Organic Acids                                                                                                               10

2.1.4.4     Proteins, Enzymes and Amino Acids                                                                            10

2.1.4.5     Minerals                                                                                                                     11

2.1.4.6     Vitamins                                                                                                                     11

2.1.4.7     Essential Oils                                                                                                              11

2.1.5       Nutritional Content of Honey                                                                                      11

2.1.6       Medicinal Uses of Honey                                                                                           13

2.1.6.1     Other Uses of Honey                                                                                                 14

2.2          Cinnamon                                                                                                                   14

2.2.1       History and Origin of Cinnamon                                                                                 14

2.2.2       Varieties of Cinnamon                                                                                                15

2.2.3       Plant Hierarchy                                                                                                             16

2.2.4       Macroscopic Characteristics                                                                                         16

2.2.5       Constituents of Cinnamon                                                                                           17

2.2.6       Nutritional Contents and Antibacterial Properties of Cinnamon                                  19

2.2.7       Health Benefits and Uses of Cinnamon                                                                      19

2.3          The Human Respiratory Tract                                                                                     21

2.4          Description of the Organisms                                                                                      23

2.4.1       Escherichia coli23

2.4.2       Pseudomonas aeruginosa24

2.4.3       Staphylococcus aureus25

2.5          Phytochemicals                                                                                                          27

2.5.1      Classification of Phytochemicals                                                                                27

 

CHAPTER THREE

3.0         Materials and Methods                                                                                                 28

3.1         Study Area                                                                                                                   28

3.2         Collection of Materials                                                                                                 28

3.2.1      Preliminary Test for the Confirmation of the Purity of Honey                                     28

3.2.1.1   Dissolution Test                                                                                                           28

3.2.1.2   Crystallization Test                                                                                                       28

3.2.1.3    Flame Test                                                                                                                   28

3.3         Processing Of Herbal Sample                                                                                      29

3.4         Physicochemical and Phytochemical Screening of Honey and Cinnamon Bark          

              Powder Extracts                                                                                                           29

3.4.1      Physico-Chemical Screening Of Honey                                                                       29

3.4.1.1   Moisture Content                                                                                                          29

3.4.1.2   Ash Content                                                                                                                 30

3.4.1.3   Water Activity                                                                                                              30

3.4.1.4   Color                                                                                                                            30

3.4.1.5   pH                                                                                                                                30

3.4.2      Phytochemical Screening of Cinnamon Bark Powder Extract                                       30

3.4.2.1   Test for Flavonoids                                                                                                      30

3.4.2.2   Test for Alkaloids                                                                                                         30

3.4.2.3   Test for Tannins                                                                                                           30

3.4.2.4   Test for Phenols                                                                                                           30

3.4.2.5   Test for steroids                                                                                                            31

3.5          Culture Media Preparation                                                                                          31

3.6          Isolation of Organisms                                                                                                31

3.7          Identification and Confirmation of Isolated Bacteria from Respiratory                      

               Tract Infections                                                                                                           31

3.7.1       Biochemical Tests                                                                                                      31

3.7.1.1    Catalase Test                                                                                                               31

3.7.1.2    Citrate Utilization Test                                                                                                 32

3.7.1.3    Coagulase Test                                                                                                             32

3.7.1.4    Methyl Red (MR) Test                                                                                                 32

3.7.1.5    Oxidase (Cytochrome Oxidase) Test                                                                           32

3.7.1.6    Indole Test                                                                                                                  33

3.7.1.7    Voges-Proskauer (VP) Test                                                                                          33

3.8          Isolation and Purification of Isolates                                                                            33

3.9          Antibacterial Activity Testing of Honey                                                                       33

3.9.1       Preparation of Dilution                                                                                                33

3.9.2       Agar Well Diffusion Technique                                                                                  34

3.9.3       Determination of Minimum Inhibitory Concentration (MIC) and Minimum

               Bactericidal Concentration (MBC) of Honey.                                                             34

3.91        Antibacterial Activity Testing of Cinnamon                                                                 35

3.91.1     Processing of Herbal Sample                                                                                       35

3.91.2     Preparation of Dilution                                                                                                35

3.91.3     Agar Well Diffusion Technique                                                                                   35

3.92        Synergistic Testing of Cinnamon Bark Powder and Honey                                         36

3.92.1     Agar Well Diffusion Technique                                                                                  36

3.92.3     Wet Disk Diffusion or Double Disk Diffusion Technique                                          36

 

CHAPTER FOUR

RESULTS                                                                                                                            38-50

 

CHAPTER FIVE

5.0 DISCUSSION, CONCLUSION AND RECOMMENDATION                                             51

5.1 DISUSSION                                                                                                                          51

5.2 CONCLUSION                                                                                                                     53

5.3 RECOMMENDATION                                                                                                         54

 

REFERENCES                                                                                                                       55-60

APPENDIX

 

 

 


 

 

LIST OF TABLES


Table 2.1   Nutritional Content of Honey


Table 2.2   Constituents of Cinnamon


Table 1      Physico-chemical Analysis of the Analyzed Honey Sample


Table 2      Phytochemical Analysis of Ethanol and Aqueous Extracts of Cinnamon Bark Powder


Table 3      Colonial Morphology of the Isolates


Table 4      Biochemical Analysis of the Isolates


Table 5      Zones of Inhibition Produced by the Honey against the Isolates


Table 6      MIC and MBC of Honey against the Isolates


Table 7      Zones of Inhibition Produced by Ethanol Extract of Cinnamon Bark Powder against the Isolates


Table 8      Zones of Inhibition Produced by Aqueous Extract of Cinnamon Bark Powder against the Isolates


Table 9      Zones of Inhibition Produced by Synergistic Test Using Agar well Diffusion Technique against the Isolates


Table 10    Zones of Inhibition Produced by Synergistic Test Using Wet Disk Diffusion Technique against the Isolates

 

 


 

 

 

CHAPTERONE


1.0   INTRODUCTION

Honey is a sweet food made by bees using nectar from flowers. The variety produced by honey bees (the genus Apis) is the one most commonly referred to and is the type of honey collected by beekeepers and consumed by humans. The various species of Apis include; Apisandreniformis, Apisflorea, Apisdorsata,Apiscerana, Apiskoschevnikovi, Apismellifera,Apisnigrocinta (Silveira etal., 2002).

Honey gets its sweetness from the monosaccharides: fructose and glucose, and has about the same relative sweetness as granulated sugar (National honey Board, 2012).It has attractive chemical properties for baking and a distinctive flavor that leads some people to prefer it over sugar and other sweeteners. Most microorganisms do not grow in honey because of its low water activity of 0.6 (Bata, 2009).

Hydrogen peroxide (H202), methylglyoxal (MGO) bee defensin, pH and Osmotic effect of honey are known to be responsible for the antimicrobial effects (Mandal, 2011).

Cinnamon comes from the bark of trees native to china, India and Southeast Asia. It is a popular cooking spice in many cultures for centuries and also has a long history of use as a traditional medicine (National institutes of Healthetal.,2012).

In ancient Indian philosophy of medicine, cinnamon is used as a remedy fordiabetes,indigestion and colds. In traditional Chinese medicine, Cassia cinnamon is used for colds, flatulence, nausea, diarrhea and painful menstrual periods. It’s also believed to improve energy, vitality, and circulation. It is particularly useful for people who tend to feel hot in their upper body but have cold feet (paradise India, 2014). Cinnamon bark is used to make powders, capsules, teas and liquid extracts (National institutes of health etal., 2012)

Based on the place grown there are hundreds of varieties of cinnamon, which can be broadly classified into two varieties: Ceylon cinnamon andcassia cinnamon. Eugenol and cinnamaldehyde are the two major chemical components in cinnamon that are responsible for its health benefits (Agabalogun etal., 2013).


1.1 BACKGROUND OF THE STUDY

The primary function of the respiratory tract is to supply the body with oxygen and remove carbon dioxide. During inspiration, outside air (Oxygen) is inspired into the body which travels from either the nose or mouth down to the lungs. During exhalation,carbon dioxide is expelled into the outside air (Tuetal., 2013). Anatomically, the respiratory tract can be separated into the upper respiratory tract comprising the nasal cavity, pharynx and larynx, and the lower respiratory tract comprising the trachea, bronchi and lungs. The respiratory tract is also connected to the ears via the Eustachian tubes and thus conditions that affect the respiratory tract can also produce symptoms in the ear (Addison, 2011).The upper respiratory tract is generally considered to be the air way above the glottis or vocal cords (Sabyasachi, 2008).

Microbes that infect the respiratory tract include: Bacteria; Streptococcuspneumoniae, Staphylococcusaureus,Corynebacteriumdiphtheria, Klebsiellapneumoniae, Pseudomonasaeruginosa, Haemophilusinfluenza, Legionellapneumophila, Mycoplasmapneumoniae, Chlamydia spp., Streptococcuspyogenes, Mycobacteriumtuberculosis, Fungi: Aspergillusniger, Viruses; Rhinoviruses, Coronaviruses, Coxsackieviruses, Adenoviruses, Influenza virus, Parainfluenza virus (Udda, 2007).

Infectious diseases of the respiratory tract include; pharyngitis, common cold, influenza, otitis media, otitis externa, acute sinusitis, laryngitis bronchitis, pneumonia (which is dividedinto acute community-acquired, acute hospital-acquired and chronic in AIDS), pulmonary tuberculosis, Empyema, croup, epiglottis, bronchitis (Udda, 2007).


1.2 STATEMENT OF RESEARCH PROBLEM

Respiratory tract infection (RTI) occurs commonly in both children and adults and is a major cause of mild morbidity. It has a high cost to society, being responsible for absenteeism from school and work and unnecessary medical care and is occasionally associated with serious sequelae. It also has a direct influence on changing environment like industrialization and air pollution. Solution has been found for many infectious illness, but common cold and other RTI has been and is still a problem to man. The use of honey and cinnamon by mankind as food and medicine has a long history down to the primitive men. However, their knowledge of the efficacy of these natural products is not vast, most especially that of cinnamon bark powder.


1.3 AIM OF THE STUDY

To determine active components in honey and cinnamon bark powder and evaluate the antibacterial activities of honey and cinnamon on some isolated bacteria species identified as responsible for respiratory tract infections.


1.4 SPECIFIC OBJECTIVES

Ø  To isolate and identify some bacteria associated with respiratory tract infections.

Ø  To determine and know the active components in honey and cinnamon bark powder responsible for their antibacterial effects by physicochemical and phytochemical analysis.

Ø  To evaluate the antibacterial activities of honey and cinnamon at varied concentrations against the bacteria isolates from the respiratory tract, both synergistically and separately, by agar well diffusion, disc diffusion method and tube dilution assays.

Ø  To determine the minimum inhibitory concentration andminimumbactericidal concentration of honey against the bacteria isolates.

Ø  To determine the susceptibilities of the respiratory tract organisms to honey and cinnamon, both as synergy and separately.

Ø  To know for effective prescribing at individual patient level.

 

 

 


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